Here are some of the problematical details:
1) Most places receive lightning very infrequently, but have a steady demand for electrical energy. The smaller the area you look at the fewer the lightning strikes will hit within that area per unit time. If you build some kind of device it has to be big enough to get hit by enough lightning strikes to supply the desired energy. If it gets hit once every ten years or so, you could be waiting a long time for a return on your investment. Bigger devices cost more.
2) Lightning has a high voltage but not a huge amount of current. Controlled sources of electrical energy typically want the other way around -- lots of current at lower voltages. 120VAC is what consumers can use, and they want a steady supply of it. Voltage and phase should not drift over time. Lightning can give you tens of thousands of volts over a few milliseconds and then be gone for the rest of the day. The lightning strike may damage the equipment, and still not have as much energy as we’d like to use. The problem is that the energy is deposited all at once, instead of spread out over time.
3) Much of the energy of the lightning discharge goes into heating up the air and making the glow. The available energy at the ground is just the amount of energy required to get the electrons into or off of the ground surface.
Storing energy from lightning